Π‘ΠΈΠ½ΡΠ΅Π· Π½ΠΎΠ²ΡΡ Π±ΠΈΡΠ΄Π΅ΡΠ½ΡΡ Ρ ΠΈΡΠ°Π»ΡΠ½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΠΈ ΠΈΡ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ Π² Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠΌ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΠΈ ΡΠ²ΡΠ·ΠΈ ΡΠ³Π»Π΅ΡΠΎΠ΄-ΡΠ³Π»Π΅ΡΠΎΠ΄
![ΠΠΈΡΡΠ΅ΡΡΠ°ΡΠΈΡ: Π‘ΠΈΠ½ΡΠ΅Π· Π½ΠΎΠ²ΡΡ
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ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΠΈ ΠΈΡ
ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ Π² Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠΌ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΠΈ ΡΠ²ΡΠ·ΠΈ ΡΠ³Π»Π΅ΡΠΎΠ΄-ΡΠ³Π»Π΅ΡΠΎΠ΄](https://gugn.ru/work/2493729/cover.png)
Y. Belokon, M. Flego, N. S. Ikonnikov, M. Moscalenko, M. North, C. Orizu, V. Tararov, M. Tasinazzo, J. Chem. Soc. Perkin Trans. 1 1997, 1293 1295. «Asymmetric addition of trimethylsilyl cyanide to aldehydes catalysed by chiral (salen)TiIV complexes». Cole B.M., Shimizu K.D., Krueger C.A., Harrity J.P.A., Snapper M.L., Hoveyda A.H.- Angew. Chem. Int. Ed. 1996, 35, 15, 1668 «Discovery of Chiral… Π§ΠΈΡΠ°ΡΡ Π΅ΡΡ >
Π‘ΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅
- Π‘ΠΏΠΈΡΠΎΠΊ ΠΈΡΠΏΠΎΠ»ΡΠ·ΡΠ΅ΠΌΡΡ ΡΠΎΠΊΡΠ°ΡΠ΅Π½ΠΈΠΉ
- I. ΠΠ²Π΅Π΄Π΅Π½ΠΈΠ΅ 4 Π. ΠΠΈΡΠ΅ΡΠ°ΡΡΡΠ½ΡΠΉ ΠΎΠ±Π·ΠΎΡ
- II. 1. Π‘ΡΠ°Π²Π½Π΅Π½ΠΈΠ΅ Π±ΠΈΡΠ΄Π΅ΡΠ½ΠΎΠ³ΠΎ ΠΈ ΠΌΠΎΠ½ΠΎΡΠ΄Π΅ΡΠ½ΠΎΠ³ΠΎ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π° 6 Π
- 1. 1. ΠΠ΅ΡΠ²ΡΠ΅ Ρ ΠΈΡΠ°Π»ΡΠ½ΡΠ΅ Π±ΠΈΡΠ΄Π΅ΡΠ½ΡΠ΅ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ 6 II
- 1. 2. ΠΠΈΡΠ΄Π΅ΡΠ½ΡΠΉ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ Π’ΡΠΎΡΡΠ° (Π.Π. Trost) 8 II
- 1. 3. ΠΠΈΡΠ΄Π΅ΡΠ½ΡΠΉ ΠΊΠΎΠ±Π°Π»ΡΡ-ΡΠ°Π»Π΅Π½ΠΎΠ²ΡΠΉ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ ΠΠΆΠ΅ΠΊΠΎΠ±ΡΠ΅Π½Π° (E.N. Jacobsen) 14 II
- 1. 4. ΠΠΈΡΠ΄Π΅ΡΠ½ΡΠΉ Ρ ΡΠΎΠΌ-ΡΠ°Π»Π΅Π½ΠΎΠ²ΡΠΉ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ ΠΠΆΠ΅ΠΊΠΎΠ±ΡΠ΅Π½Π° (E.N. Jacobsen) 17 II
- 1. 5. ΠΠΈΡΠ΄Π΅ΡΠ½ΡΠΉ Π°Π»ΡΠΌΠΈΠ½ΠΈΠΉ-ΡΠ°Π»Π΅Π½ΠΎΠ²ΡΠΉ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ ΠΠΆΠ΅ΠΊΠΎΠ±ΡΠ΅Π½Π° (E.N. Jacobsen) 20 II
- 1. 6. ΠΠΈΡΠ΄Π΅ΡΠ½ΡΠΉ ΡΠΈΡΠ°Π½-ΡΠ°Π»Π΅Π½ΠΎΠ²ΡΠΉ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡ ΠΠ΅Π»ΠΎΠΊΠΎΠ½Ρ (Y.N. Belokon) 28 II
1.7 ΠΠΈΡΠ΄Π΅ΡΠ½ΡΠ΅ Π²Π°Π½Π°Π΄ΠΈΠ΅Π²ΡΠ΅ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ ΠΠΎΠ½Π³Π° (L. Gong) 33 II. 2. ΠΡΡΠ³ΠΈΠ΅ Π±ΠΈΡΠ΄Π΅ΡΠ½ΡΠ΅ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΡ 39 II. 3. Π Π΅Π°ΠΊΡΠΈΡ Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΡΡΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΈΠ»ΠΈΠ»ΡΠΈΠ°Π½ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π°Π»ΡΠ΄Π΅Π³ΠΈΠ΄ΠΎΠ² 46 II. 4. Π Π΅Π°ΠΊΡΠΈΡ Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ Π°Π»Π»ΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π°Π»ΡΠ΄Π΅Π³ΠΈΠ΄ΠΎΠ²
II. 5. Π Π΅Π°ΠΊΡΠΈΠΈ Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΡΠ°ΡΠΊΡΡΡΠΈΡ ΠΌΠ΅Π·ΠΎ-ΡΠΏΠΎΠΊΡΠΈΠ΄ΠΎΠ²
III. ΠΠΎΡΡΠ°Π½ΠΎΠ²ΠΊΠ° Π·Π°Π΄Π°ΡΠΈ
IV. ΠΠ±ΡΡΠΆΠ΄Π΅Π½ΠΈΠ΅ ΡΠ΅Π·ΡΠ»ΡΡΠ°ΡΠΎΠ² 75 IV. 1. Π‘ΠΈΠ½ΡΠ΅Π· Ρ ΠΈΡΠ°Π»ΡΠ½ΡΡ Π³Π΅ΠΊΡΠ°Π΄Π΅Π½ΡΠ°ΡΠ½ΡΡ Π»ΠΈΠ³Π°Π½Π΄ΠΎΠ² 75 IV. 2. Π Π΅Π°ΠΊΡΠΈΡ Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΡΠΈΠ°Π½ΡΠΈΠ»ΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π°Π»ΡΠ΄Π΅Π³ΠΈΠ΄ΠΎΠ² 83 IV. 3. Π Π΅Π°ΠΊΡΠΈΡ Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ Π°Π»Π»ΠΈΠ»ΠΈΡΠΎΠ²Π°Π½ΠΈΡ Π°Π»ΡΠ΄Π΅Π³ΠΈΠ΄ΠΎΠ²
IV. 4. Π Π΅Π°ΠΊΡΠΈΡ Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ ΡΠ°ΡΠΊΡΡΡΠΈΡ ΠΌΠ΅Π·ΠΎ-ΡΠΏΠΎΠΊΡΠΈΠ΄ΠΎΠ² 100 ΡΡΠΈΠΌΠ΅ΡΠΈΠ»ΡΠΈΠ»ΠΈΠ»ΡΠΈΠ°Π½ΠΈΠ΄ΠΎΠΌ
V. ΠΡΠ²ΠΎΠ΄Ρ
VI. ΠΠΊΡΠΏΠ΅ΡΠΈΠΌΠ΅Π½ΡΠ°Π»ΡΠ½Π°Ρ ΡΠ°ΡΡΡ
Π‘ΠΈΠ½ΡΠ΅Π· Π½ΠΎΠ²ΡΡ Π±ΠΈΡΠ΄Π΅ΡΠ½ΡΡ Ρ ΠΈΡΠ°Π»ΡΠ½ΡΡ ΠΊΠ°ΡΠ°Π»ΠΈΠ·Π°ΡΠΎΡΠΎΠ² ΠΈ ΠΈΡ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠ΅ Π² Π°ΡΠΈΠΌΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΎΠΌ ΠΎΠ±ΡΠ°Π·ΠΎΠ²Π°Π½ΠΈΠΈ ΡΠ²ΡΠ·ΠΈ ΡΠ³Π»Π΅ΡΠΎΠ΄-ΡΠ³Π»Π΅ΡΠΎΠ΄ (ΡΠ΅ΡΠ΅ΡΠ°Ρ, ΠΊΡΡΡΠΎΠ²Π°Ρ, Π΄ΠΈΠΏΠ»ΠΎΠΌ, ΠΊΠΎΠ½ΡΡΠΎΠ»ΡΠ½Π°Ρ)
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